Additions to and Substitutions at C-C ?-Bonds

Released on by M.F. Semmelhack
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  • Additions to and Substitutions at C-C ?-Bonds Book Detail

  • Author : M.F. Semmelhack
  • Release Date : 1992-09-08
  • Publisher : Elsevier
  • Genre : Science
  • Pages : 1322
  • ISBN 13 : 0080912478
  • File Size : 75,75 MB
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Additions to and Substitutions at C-C ?-Bonds by M.F. Semmelhack PDF Summary

Book Description: Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.

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Combining C-C ?-Bonds

Combining C-C ?-Bonds

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The guiding principle underlying the subject matter specifically compiled in Volume 5 has been to make available to the organic chemical community a sourcebook