Gold and Silver Catalysis of Carbon-Nitrogen Bond Formation and Cycloaddition Reactions

Released on by David Anthony Capretto
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  • Gold and Silver Catalysis of Carbon-Nitrogen Bond Formation and Cycloaddition Reactions Book Detail

  • Author : David Anthony Capretto
  • Release Date : 2011
  • Publisher :
  • Genre :
  • Pages : 131
  • ISBN 13 : 9781124717418
  • File Size : 30,30 MB
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Gold and Silver Catalysis of Carbon-Nitrogen Bond Formation and Cycloaddition Reactions by David Anthony Capretto PDF Summary

Book Description: This dissertation describes four research topics all based on the catalytic reactivity of silver and gold complexes. Chapter I details work towards the development of a silver catalyzed nitrene transfer reaction with high activity for benzylic and even alkyl C-H bonds. Chapter II describes the development of a gold(III) catalyzed aryl C-N bond formation. Chapter III describes the synthesis and exploitation of a new diaziridine molecule for use in gold(I) catalyzed cycloaddition chemistry with terminal alkynes. Chapter IV describes efforts toward the natural product synthesis of oligomers based on the resveratrol molecule.

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Catalysis By Gold

Catalysis By Gold

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Gold has traditionally been regarded as inactive as a catalytic metal. However, the advent of nanoparticulate gold on high surface area oxide supports has demon