Reagents for Silicon-Mediated Organic Synthesis

Released on by Philip L. Fuchs
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  • Reagents for Silicon-Mediated Organic Synthesis Book Detail

  • Author : Philip L. Fuchs
  • Release Date : 2013-05-30
  • Publisher : John Wiley & Sons
  • Genre : Technology & Engineering
  • Pages : 816
  • ISBN 13 : 1118636139
  • File Size : 44,44 MB
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Reagents for Silicon-Mediated Organic Synthesis by Philip L. Fuchs PDF Summary

Book Description: Over the last three decades the importance of organosiliconchemistry has greatly increased because it has opened a number ofnew synthetic strategies. Silicon reagents are usually low-cost,versatile and allow a wide range of reactions. This is the firstHandbook to compile essential Silicon containing reagents and makesuse of the leading reagent database e-EROS. Another hotvolume in the series Handbooks of Reagents for OrganicSynthesis, this is a must-have resource for all syntheticchemists working in drug development and medicinal chemistry. For the selection the Editor focussed on three key syntheticapproaches with the greatest impact: 1. Use of silicon as a 'temporary tether' by unifying a reactivepair of functional groups and taking advantage of theirtemplate-biased intramolecular cyclization. 2. The specific use of the silane functionality as a heterot-butyl group, often colloquially referred to as the use ofsilicon as a 'fat proton'. 3. The use of the Brook rearrangement as an 'anion relaystratagem'. A new feature in this Handbook is the reagent finder, analphabetically organized lookup table arranged by organicfunctionality and specific structure of the silicon atom to whichit is bound.

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