Ziegler-Natta Catalysts Polymerizations

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  • Ziegler-Natta Catalysts Polymerizations Book Detail

  • Author : John Jr. Boor
  • Release Date : 2012-12-02
  • Publisher : Elsevier
  • Genre : Technology & Engineering
  • Pages : 689
  • ISBN 13 : 0323143415
  • File Size : 72,72 MB

Ziegler-Natta Catalysts Polymerizations by John Jr. Boor PDF Summary

Book Description: Ziegler-Natta Catalysts and Polymerizations reviews the general aspects of Ziegler-Natta catalysts and polymerizations of olefins, dienes, and many other types of monomers. Topics covered include the physical state of the polymer during polymerization; modification of Ziegler-Natta catalysts by third components; and termination of polymer chain growth. The oxidation state of catalysts and active centers is also discussed, along with copolymerizations and block polymerizations. This book is comprised of 23 chapters and begins with an overview of Ziegler-Natta catalysts and polymerizations, their historical origins, scientific and commercial importance, and major advances in polymer science. The next chapter focuses on definitions and stereochemistry of Ziegler-Natta catalysts, together with analytical methods used to identify and quantitatively measure their structures. Some of the polymers produced commercially with Ziegler-Natta catalysts are considered. The discussion then turns to mechanisms for initiating and propagating olefins; mechanisms for stereochemical control of conjugated and nonconjugated dienes; and the basic kinetic parameters that characterize Ziegler-Natta polymerizations. This monograph is written especially for chemistry and engineering graduate students and for industrial chemists, engineers, and managers who may become involved in a Ziegler-Natta problem.

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Ziegler-Natta Catalysts Polymerizations

Ziegler-Natta Catalysts Polymerizations

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Ziegler-Natta Catalysts and Polymerizations reviews the general aspects of Ziegler-Natta catalysts and polymerizations of olefins, dienes, and many other types

Ziegler Catalysts

Ziegler Catalysts

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Forty years after Ziegler's discovery of the "Aufbaureaktion" and low-pressure ethene polymerization, transition metal catalyzed olefin and diolefin polymerizat